(4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)(trifluoromethyl-κC)palladium(II)
نویسندگان
چکیده
In the title compound, [Pd(CF3)(C6H4F)(C6H16N2)], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand and by one C atom each from a 4-fluoro-phenyl and a tri-fluoro-methyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°.
منابع مشابه
Crystal structure of (4-fluorophenyl-κC 1)iodido(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)palladium(II)
In the title compound, [Pd(C6H4F)I(C6H16N2)], the Pd(II) atom is coordinated by two N atoms from the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand, a C atom of the 4-fluoro-phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83....
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014